EPR simulator is under construction! Proceed with care!
Currently available simulations
- Isotropic EPR spectra. This is the most developed page with lots of help, examples, some exercises.
- Electron with no hyperfine interaction. This page is a very simple illustration of the effect of anisotropy on EPR spectra.
- Copper complexes with axial symmetry. Lineshapes of copper complexes with different g and hyperfine tensors and different liewidth.
- Restricted motion of nitroxides. Effect of both isotropic and anisotropic tumbling of nitroxides on their EPR spectra (neither MOMD nor SRLS approaches are included at present)
- Isotropic EPR spectra of rigid diradicals. EPR spectra of diradicals in fluid solutions for different J/a ratios.
- Triplet EPR spectra. EPR spectra of organic triplets with different zero-field splitting parameters D and E.
- Chemical exchange. The effect of chemical exchange on EPR spectra.
Why do I need the EPR simulator?
This site was designed to show simulated EPR spectra in an interactive way: the spectrum is continuously updated as the parameters are changed. The main aim is to illustrate how different parameters affect EPR spectra. The examples were carefully chosen to show commonly-observed features and typical spectral shapes. The range of parameters is restricted to reasonable values, and care was taken not to produce wrong or impossible spectra. The simulator can be used to:
- learn how to analyse and assign EPR spectra
- get a feel for the sensitivity of EPR line shape to different parameters
- explore the different types of EPR spectra for a particular class of compounds and learn how to recognise them
Compatibility and known issues
- This simulator was designed for a computer with a mouse. Many features will be disabled on touch devices (e.g., smartphones or tablets), and some features will be buggy. Please use desktop/laptop computers! I am planning to develop a version for touch devices in the future but it will take time.
- The simulator will not work at all with early versions of Internet Explorer (earlier than IE10). Please use other browsers or update your Internet Explorer.
- The height of the spectrum is limited in some early version of Opera. This will be fixed.
- All calculations and most features are wrtten in JavaScript. Do not disable JavaScript for this site!
- For most simulations, small spectrum files (4 kB) are frequently downloaded, therefore good internet connection is essential for the simulator to work. In addition, the simulator itself is a significant download (ca. 500 kB) so be careful if you have very limited internet allowance.